A sensitive method for atmospheric sulfur dioxide determination by reaction cell inductively coupled plasma mass spectrometer
Data files
Oct 27, 2025 version files 649.28 MB
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calibration_curve.csv
4.47 KB
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calibration_curve.xls
225.35 KB
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Dependence_of_sampling_flow_rate.csv
3.51 KB
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Dependence_of_sampling_flow_rate.xls
178.41 KB
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Dependence_of_the_concentrated_solution_(CSV).zip
8 KB
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Dependence_of_the_concentrated_solution.zip
78.96 KB
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Dependence_of_volume_of_concentrated_solution_(CSV).zip
6.23 KB
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Dependence_of_volume_of_concentrated_solution.zip
81.48 KB
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Optimization_of_O2_flow_rate.zip
648.54 MB
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README.md
3.31 KB
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The_effects_of_potential_interferences.csv
4.47 KB
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The_effects_of_potential_interferences.xls
151.04 KB
Abstract
A sensitive method for sulfur dioxide (SO2) determination was developed with a reaction cell inductively coupled plasma mass spectrometer (ICP-MS) by preconcentrating SO2 from gas samples in solutions. O2 flow rate was set at 0.7 mL min-1 for optimal S/N ratio at m/z 48 (32S16O+). Favorable conditions to prepare SO2 concentrated solutions, including sampling flow rate, the volume of concentrated solution, the number of perfluoroalkoxy alkane (PFA) bubble absorption bottles, and the composition of concentrated solution, were investigated using SO2 in nitrogen gas reference materials within the range of 5.00 parts per billion (ppb) to 1.00 parts per million (ppm). A limit of detection (LOD) of 0.11 ppb was achieved, corresponding to 100 L 5.00 ppb SO2 with a sampling flow rate of 0.5 L min-1. This method also showed favorable selectivity in the assay of atmospheric SO2 level, providing its promising further application in monitoring gaseous environmental pollutants.
Dataset DOI: 10.5061/dryad.tb2rbp0dk
Description of the data and file structure
This dataset contains the data required to replicate atmospheric sulfur dioxide determination by inductively coupled plasma mass spectrometer in collision cell technology mode. O2 flow rate on CCT mode was optimized to realize optimal S/N ratio at m/z 48 (32S16O+). 5 nmol mol-1-1.00 μmol mol-1 SO2 in nitrogen gas reference materials proved the feasibility of the method under different conditions to prepare SO2 concentrated solution samples such as sampling flow rate, the volume of concentrated solution, the number of PFA bubble absorption bottles, the composition of concentrated solution and so on. For the purpose of monitoring SO2 level in the ambient atmosphere, sulfur-containing gases and other co-existing air pollutants that may cause interference were also evaluated. The assay of atmospheric levels was a proof to validate the analytical performance of the proposed strategy on SO2 quantification with ICP-MS in a practical application.
Files and variables
File: Optimization_of_O2_flow_rate.zip
Description: These files contain real-time response videos of the instrument when optimizing the oxygen flow rate from 0.2 mL min-1 to 1.0 mL min-1 on the signal intensity of 32S16O+ from a 100 μg L-1 S standard solution and background.
File: calibration_curve.xls; calibration_curve.csv
Description: These files contain data of a calibration curve derived from 0.0 μg L-1, 10 μg L-1, 20 μg L-1, 50 μg L-1, 100 μg L-1, 200 μg L-1, 500 μg L-1 S standard solutions.
File: Dependence_of_sampling_flow_rate.xls; Dependence_of_sampling_flow_rate.csv
Description: These files contain data on the dependence of sampling flow rate on the mass concentration of sulfur in the concentrated solution sample and absorption efficiency from 0.3 L min-1 to 0.9 L min-1.
File: Dependence_of_the_concentrated_solution.zip; Dependence_of_the_concentrated_solution_(CSV).zip
Description: These files contain data on the dependence of the volume of concentrated solution on the mass concentration of sulfur in the concentrated solution sample and absorption efficiency from 10 mL to 70 mL.
File: The_effects_of_potential_interferences.xls; The_effects_of_potential_interferences.csv
Description: These files contain data on the effects of potential interference encountered on SO2 determination.
File: Dependence_of_volume_of_concentrated_solution.zip; Dependence_of_volume_of_concentrated_solution_(CSV).zip
Description: These files contain data on the dependence of the concentrated solution and SO2 sources on the mass concentration of sulfur in the concentrated solution sample and absorption efficiency.
Code/software
Any version of Microsoft Office can be used to view the data (The files uploaded as formatted .xls and unformatted CSV files). All players that support the MP4 format can view the videos uploaded.
Access information
Other publicly accessible locations of the data:
- None
Data was derived from the following sources:
- None
