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Growth of carbon nanofibres on molybdenum carbide nanowires and their self-decoration with noble-metal nanoparticles

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Sep 04, 2020 version files 95.13 KB

Abstract

High specific surface area makes carbon nanofibres suitable for catalyst support. Here we report on optimisation of carbon nanofibre (CNF) growth on molybdenum carbide nanowires (MoCNW) by direct carburization of Mo6S2I8 nanowire bundles. Typical CNFs obtained by this method are several hundreds of nanometres long at a diameter of 10-20 nm. We show that nanofibre growth does not depend on the initial morphology of the nanowires: nanofibres grow on individual bundles of MoCNW, on dense networks of nanowires deposited on silicon substrate, and on free-standing nanowire foils. We find that carbon nanofibres remain firmly attached to the nanowires even if they are modified into Mo2C and further into MoS2 nanowires. The method thus enables production of a novel hybrid material composed of MoS2 nanowires densely covered with carbon nanofibres. We have additionally shown that the obtained CNFs can easily be self-decorated with platinum nanoparticles with diameters of several nanometres directly from water solution at room temperature without reducing agents. Such efficient synthesis and decoration process yield hybrid platinum/CNF/molybdenum-based NW materials, which are a promising material for a wide range of possible future applications, including sensitive sensorics and improved catalysis.